Dr Alex Ibhadon

Dr Alex Ibhadon

Reader, Catalysis and Reactor Engineering

Faculty and Department

  • Faculty of Science and Engineering
  • School of Engineering

Qualifications

  • BSc
  • MSc
  • PhD / DPhil (University of Birmingham)

Summary

A.O.Ibhadon PhD CChem FRSC MIM SFHEA MSPE

Reader, Catalysis and Reactor Engineering

Visiting Professor, Panjab University, Chandigarh, India

Co-founder, Stoli Catalysts ( a Spin-Out Company)

Dr Ibhadon graduated with a doctorate in Physical Polymer Chemistry from the University of Birmingham following the award of a Commonwealth Scholarship. PhD work (distinction in first year assessment), involved studying the mechanical properties and crystallization behaviour of semi-crystalline polymers. Work on crystallization after ‘partial melting’ was put into commercial exploitation in the ‘Thermoforming’ Operations at Metal Box (Oxon), enabling the manufacture of plastic products with enhanced fracture toughness, impact resistance as well as reduced environmental stress cracking. The results from this work also formed the basis of eight articles published in the Journal of Applied Polymer Science, including articles such as ‘Crystallization Regimes in Semi-crystalline Polymers’, ‘Physical Ageing in Isotactic Polypropylene’ and ‘Strain hardening behaviour in Semicrystalline Polymers’ and Fracture Mechanics in semicrystalline polymers

Employment as a postdoctoral research fellow, School of Chemical Engineering and Advanced Materials, Newcastle University and a lectureship appointment at the University of Hull, followed my PhD study at the University of Birmingham and developing my research in Catalysis and Reactor Engineering at the University of Hull. Main areas of research focus include decarbonization , sustainable energy generation from renewable sources and synthesis , using novel non noble metal catalysis and catalytic reactors. Of particular interest is the synthesis of ammonia and hydrogen using non-thermal plasma catalysis using either desalinated water and nitrogen or biomethane as feedstock(microwave plasma decomposition to hydrogen and solid carbon).

Dr Ibhadon is a Reader in Catalysis and Reactor Engineering at the University of Hull, Senior Fellow, Higher Education Academy and a Fellow and Chartered Chemist of the Royal Society of Chemistry (CChem FRSC). Dr Ibhadon has received > £7.08M in research funding from (twenty two grant awards) and is a co-founder of a Spin-Out Company between the UoH and the University of Warwick. Dr Ibhadon has published over 76 articles in leading journals in the area of Catalysis and Chemical Synthesis and made over 94 national and international conference presentations.

Dr Ibhadon is a review for several organizations including the EU, EPSRC, UKRI, FLF, Netherlands, Estonia, Russia, Israel and several high impact journals such as Applied Catalysis B, Energy and Environmental Science, ChemCatChem, Plasma Science and Technology and American Chemical Society Journals. Dr Ibhadon is the Editor of Frontiers in Heterogeneous Catalysis, Catalyst and Synthesis amongst others. Dr Ibhadon is an advisory board member of the EPSRC Center for Energy Systems Integration (CESI/HI-ACT) and a consultant to many Chemical and Energy industries with contributions in hydrogen and ammonia generation as well as low carbon materials for applications in construction and energy storage

Dr Ibhadon coordinated the EU project on Microwave, Acoustic and Plasma Synthesis (2013-2017) that was described by Retell Publications as a 'research and innovation success story). An extensive array of strategic academic and industrial partnerships in the UK , EU, USA and Asia have enabled Dr Ibhadon to make significant international reach and impact in energy generation as well as contributing to some countries in the global South to be more resilient in the face of global challenges relating to water and sanitation, antimicrobial technology and environmental monitoring

Dr Ibhadon is a visiting professor in catalysis to Panjab University, Chandigarh, India (a top ranking Indian University)

Catalysis, of the focus areas of my research work, is the bedrock of manufacturing in the Chemical, Pharmaceutical and Allied Industries. The Chemical industry employs > 67% of EU workforce and contributes > £50BN to UK GDP. Catalysis is an internationally important and competitive arena. For example, catalysis driven Artificial Photosynthesis provides energy security and climate mitigation, enables Smart Cities and Sustainable Futures, while Catalysis driven Nitrogen Fixation ensures food security for > 4.5BN people by providing fertilizers for agriculture through the Haber Bosch Ammonia process; this process use heterogeneous catalyst materials that have an annual market turnover of $220BN. Thirdly, decarbonization of energy systems and protection of our global ecosystems and bio-diversity, is only possible with catalyst materials as they will enable sustainable manufacturing, renewable energy production, and innovations in green technologies, and support for the Circular Economy while also providing millions of job opportunities, globally. Catalysis is a priority technology area for the UK via EPSRC/UKRI research portfolios and is the reason for UK Catalysis HUBs at Cardiff, Manchester and Bath Universities and other UK institutions.

Research Theme

New Generation of Renewable energy Technologies

We carry out research work on the decarbonization of the energy system as this is required to enable the UK and other nations to meet their national determined contributions (NDC) as well as obligations set out in the Paris Climate Change Agreement. To achieve these objectives requires the ultimate replacement of fossil fuels with renewable alternatives that have the capability and flexibility for long-term and large-scale storage in new kind of energy storage compounds. In this regard, our work is focused mainly on the production, storage and transport of hydrogen from renewable routes. Due to its high energy density (about 3 times higher, on weight basis) than the energy density of conventional fuels, hydrogen (H2), is a clean and feasible alternative to carbon-based fuels and decarbonization of the UK energy sectors, e.g. the transport sector, by switching to H2 fuel will not only help the UK Aviation meet its net-zero CO2 emissions target, it will also contribute to enabling the UK government to meet its targeted emission reduction obligations. This is the basis of our current energy based projects listed below.

1. The production of green Ammonia and Hydrogen for an End-to End industrial fuel switching applications in transport, shipping or maritime, combustion and aviation or Fuel Cells

2. The production of Ammonia and its cracking to Hydrogen via atmospheric pressure desalination and Non-Thermal Plasma Catalysis

3. Renewable energy integration via Modelling and Simulation

4.Carbon dioxide utilization via conversion into fuels/renewable energy generation such as dimethyl ether (DME) or raw materials such as methanol using physical or chemical methods offers an approach to sustainably and economically abate and recycle CO2 and eliminate the economic liability and health & safety concerns associated with geological CO2 storage in carbon capture and storage (CCS) technology. Various technologies, including thermocatalysis, electrocatalysis, photocatalysis, and biochemical technology, can be used for this purpose. Of these, the solar-driven photo-catalytic process has proved to be a promising technology (Roy et al, ASC Nano, 2010, 4, 1259-1278). However, photo-catalytic technology has low conversion efficiency and low utilization of solar energy, which vary significantly from one technology to another. To tackle this challenge, a photo-catalytic system that can make efficient use of solar energy is the most desired development. Solar light absorption and electron transportation in conventional photocatalytic materials are difficult especially in single photocatalyst systems because: (a) semiconductor has a lower light absorption capability than Phytochroms, although ionic doping and semiconductor coupling have been used to broaden the spectrum responsive range.

Recent research indicates that introducing disordering and defected surfaces can significantly increase light absorption (Chen et al, Science, 2011, 331. 746-750); (b) photo-catalytic systems are, unlike Phytochroms, found in nature, in which the photo-generated electrons can be exploited by 100%. Compared to phytochroms, the electron transportation velocity of semiconductors is significantly lower, resulting in reduced separation efficiency of the photo-generating carriers. Although P/N hetero-junctions have been reported, the separation effect is not significant; (c) nanofabrication of photo-catalysts is an effective way to improve the photo-catalyst activity. Recent studies indicate that the photo-generating carriers can be effectively separated by the space confinement of nano-domains (Liu et al, J. Am. Chem. Soc., 2010, 132 14385-14387).

5.Photoelectrochemical CO2 reduction and H2O splitting

The photoelectrochemical reduction of CO2 competes with water reduction in aqueous media, i.e. H2 generation and the direct photo reduction is a challenge because CO2 is thermodynamically stable, showing a high energy barrier that impedes its activation and conversion in a multistep and complicated reaction pathway. For this reason, the conversion efficiency and reaction selectivity are largely compromised. The main CO2 reduction products are C1 (CO, CH4, CH3OH, CH2O, and HCOOH) and C2 (C2H4, C2H5OH, and CH3COOH), which are more desirable for applications in energy storage and transportation and as fuels because of their higher energy density and value. Electrochemical reduction allows the production of C1 with > 95 Faradaic efficiency, C2 with 60 % FE and C3 products with 8 %. The main advantage of a PEC reactor compared to a photocatalytic device is that its compartmentalized design allows for the separation of reduction and oxidation products. PEC reactor design for CO2 reduction is limited, however, the designs proposed for electrochemical CO2 reduction can be adopted and these are based on a cathode electrocatalyst immobilized in a gas diffusion layer, which overcomes the limitations of low CO2 concentration at the cathode interface. We use selective ion-exchange membrane to separate the anolyte and catholyte and surface modification to improve photoelectrode efficiency and stability

Density Functional Theory Computational Analysis of Catalytic reactions and reactors.

An international esteem and record of accomplishment in research in catalysis and advanced materials has been underpinned by substantial and significant research funding from the EU, the UK Department of Business, Energy and Industrial Strategy (BEIS), Royal Society, Engineering and Physical Sciences Research Council, the Newton, NetZero Innovation as well as the Commonwealth with total research income > £6.6M, with recent grants since 2016 listed below:

2023: UKRI/EPSRC - Ammonia-Hydrogen Network for the Humber Cluster (100k)

2023: VUBA- Testing of Polyols and acrylonitrile binders for surfacing applications (33k)

2022: BEIS IHA - End to End Fuel Switching for Industrial Applications (400k) under the NetZero Innovation Portfolio Programme

2021: Royal Society; Development and Testing of high-performance Catalysts for an on-board cracking of ammonia for hydrogen-powered transport system (£12000).

2021: Royal Society; Design of Thallium Nitride Photoelectrodes for Dimethyl Ether Synthesis (£12,000)

2021: EPSRC Network Hydrogen; Development of a compact and highly efficient On-board ammonia cracking system to produce hydrogen in a hydrogen-fueled long haul civil airliner (£50,000)

2021: Net Zero Innovation; Development and analysis of a novel liquid ammonia energy Storage (LNHES) technology integrated to different energy systems (£40,000)

2021: United Kingdom Carbon Capture and Storage Research Centre (£30,000), The Development of an energy-efficient and cost-effective catalytic regeneration system in the post-combustion CO2 capture process)

2021 Conversion of Waste to Biogas-Global Challenge Research Fund 2020: Synthesis of Inorganic Sensors Commonwealth (£39,820.38)

2019: Global Challenge Research Fund (£28,857)

2019: New Coating Technology for chemical synthesis EU Leadership grant of €1,177,925 (awarded to Spin Out)

2018: Microfluidic Sensors Global Challenge (£26,536)

2018: Advanced Materials for Water Treatment Newton Fund (£37,100)

2018: Photocatalytic Quantum Dots Newton Fund (£15,400)

2017: Micro-Reactors Active Pharm for APIs, EU Funding (£46,000)

2016: Advanced Nanoporous Materials Newton Fund (£70,000)

2016: Catalyst Coated Tubular Reactors Innovate UK £550,000, (awarded to Spin-Out)

2016: Catalyst Coated Tubular Reactors EU Proof of Concept (PoC) Grant €150,000 (awarded to Spin-out)

2016: Catalyst Coated Tubular Reactors EPSRC £35,000 (awarded to Spin-out)

2016: Microwave, Acoustic and Plasma Synthesis EU FP7 £3,600,000

2021 Research Excellence Framework Articles ( 5 3* articles)

1. Dehydroacetic acid Derived Schiff base as Selective and Sensitive Colorimetric Chemosensor for the Detection of Cu (II) ions in Aqueous Medium, 10.1016/j.microc.2020.104705;2020

2. Low temperature plasma-catalytic NOx synthesis in a packed DBD reactor: effect of support materials and supported active metal oxides10.1016/j.apcatb.2016.04.055;2016

3. Novel synthesis of thick wall coatings of titania supported Bi poisoned Pd catalysts and application in selective hydrogenation of acetylene alcohols in microreactors10.1039/c4lc01066c; 2015

4. Stabilization of Pd3−xIn1+x polymorphs with Pd-like crystal structure and their superior performance as catalysts for semi-hydrogenation of alkynes

10.1002/cctc.201900391;2019

5. Ultrasound- and microwave-assisted preparation of lead-free palladium catalysts: effects on the kinetics of diphenylacetylene semi-hydrogenation, 10.1002/cctc.201402999;2015

Current Projects

1. BEIS funded end-to end fuel switching for Industrial application:

Plasma Catalysis for Ammonia Synthesis and Cracking to

Hydrogen (BEIS)

2. UKRI/ESPRC: Ammonia-Hydrogen Network for the Humber

Cluster

3.Royal Society funded: Development of Thallium Nitride

Photocathodes for Dimethyl Ether Synthesis

4.EPSRC Network Hydrogen funded: Development of a compact and

highly efficient on-board ammonia cracking system to produce

hydrogen in a hydrogen-fueled long haul civil airliner

5.Net Zero Innovation funded: Development and analysis of a novel

liquid ammonia energy storage (LNHES) technology integrated to

different energy systems

6.United Kingdom Carbon Capture and Storage Research Centre

funded: The Development of an energy-efficient and cost-effective

catalytic regeneration system in the post-combustion CO2 capture

process)

7.Royal Society funded Development and Testing of high

performance Catalysts for an on-board cracking of ammonia for

hydrogen-powered transport system.

8.EU funded: The Synthesis of Active Pharmaceutical Ingredients

Publications since 2016

J. Owolabi, M. Irshad, A. Temitope, A.Ibhadon, E.Oko; Solar and Geothermal-Based Cogeneration Technologies Encyclopedia of Renewable Energy, Sustainability, and the Environment, 2024.

Weiyi Hao, Hanming Zhang, Yiran Teng, Alex O. Ibhadon, & Fei Teng, Electrocatalytic H2 Production and Synergistic Formaldehyde Degradation, ACS App. Energy Mater. 2024, 7, 1, 72–83 https://doi.org/10.1021/acsaem.3c02215

Z. Li, J. Zhang, Y. Teng, H. Zhang, X. Guo, X. Zhang, Z. Li, G. Cheng, A.O. Ibhadon, F. Teng, obviously boosting charge separation efficiency and photocatalytic activity of CdS by a simple fluorination method, Inorganic Chemistry Communications 2023, 155 ,111060; https://doi.org/10.1016/j.inoche. 2023.111060

Waris, Abul Hasnat, Shumaila Hasan, Sayfa Bano, Saima Sultana, Alex O Ibhadon, Mohammad Zain Khan, Development of nanozyme based sensors as diagnostic tools in clinic applications: a review, J. Mater. Chem. B, 2023. doi: 10.1039/d3tb00451a

Li Wang, Ben Ma, Yiran Teng, Wansheng Ruan, Gangya Cheng, Xinyu Zhang, Zhihui Li, Zhian Li, Chengyue Han, Alex O Ibhadon, Fei Teng, Boosting photocatalytic nitrogen reduction reaction by Jahn-Teller effect, Jour. Colloid and Interface Science https://doi.org/10.1016/j.jcis.2023.06.191

Boosting hydrogen production of uniform CuCo-ZIF nanododecahedrons by bimetal node and glycerol

Q.Wang, W.Ruan, Y.Teng, B.Ma, X.Zhang, X.Yuan, Z.Li, W.Jiang, F.Teng, A.O.Ibhadon, Materials Today Chemistry, 2023, 28, 101359

W.Ruan, C.Yuan, F.Teng, H.Liao, A.O.Ibhadon; Boosting hydrogen production in ultrathin birnessite nanosheet arrays-based electrolytic cell by glycerol and urea oxidation reactions, Materials Today Chemistry, 2022, 26, 101086 doi.org/10.1016/j.mtchem.2022.101086

Khan, N., Hakeem, A., Sultana, S., Ibhadon, A., Khan, M.Z., Effective toxicity assessment of synthetic dye in microbial fuel cell biosensor with spinel nanofiber anode, Jour. Env. Chem.Eng. 2022. 10.1016/j.jece.2022.107313

Shehu, H., Orakwe,I., Abunomah, O., Ogunlude, P., Ogoun, E., Ramalan, M., Aisueni, F., Oko, E., Ibhadon, A., Gad-briggs, A., Giannopoulos, I., Giwa, A. and Gobina, E. Development of dense membranes for high density H2 production from NH3 catalytic decomposition for PEM fuel cells power in long-haul passenger aircraft transportation, TechConnect Briefs 2022, 134-137 https://briefs.techconnect.org/wp-content/volumes/TCB2022/pdf/310.pdf

Wansheng Ruan, Shuyu Liang, Chen Yuan, Weiyi Hao, Zilin Lu, Dan Wang,Gangya Cheng Qiuheng Wang, Wenjun Jiang , Alex O. Ibhadon, Fei Teng, Boosted electrocatalytic hydrogen production by methylene blue and urea and synergistic electrooxidation degradation, Materials Today Energy, 2021, 22, 100880 Chen Yuan; Weiyi

Hao; Shuyu Liang; Zilin Lu; Ben Ma; Jiawei Zhang; Wansheng Ruan; Zain Ul Abideen; Wenjun Jiang; A.O.Ibhadon, Fei Teng. Promoted N≡N by Oxygen and boosted Ammonia Production over Bi4O5Br2, Molecular Catalysis 2021, 515, 111913. https://doi.org/10.1016/j.mcat.2021.111913

Southouse, Jamie; Lazzarini, Laura; Ibhadon, A O; Francesconi, Maria “Ultra-Small FeS2 Nanoparticles for Highly Efficient Chemoselective Transfer Hydrogenation of Nitroarenes" Royal Society of Chemistry New Journal of Chemistry, 2021, 45, 17808-785 doi: 10.1039/d1nj03297f

Devika Vashisht, Sugandha Sangar, Manpreet Kaur, Ekta Sharma, Aseem Vashisht, A. O. Ibhadon, Shweta Sharma, S. K. Mehta, Kulvinder Singh -Biosynthesis of Silver Nanospheres, their Kinetic profile and Optical Sensing of Mercury and Chlorite ions in aqueous solution, Environmental Research, 2021, 197, 111142 https://doi/org/10.1016/j.envres.2021.111142

Devika Vashisht & A.O.Ibhadon, Isothiocyanates: Chemical Substance for Environmental Remediation: in Spectrum of Isothiocyanates, its Chemistry and Applications, Nova Publishers (ISBN:978-1-53616-478-7: 2021), Chemistry Research and Applications, Imprints, Nova, Science and Technology, Special Topics, Jan 2021 (https://novapublishers.com/shop/spectrum-of-isothiocyanate-chemistry-and-its-applications/)

Bhaskar S. Patil, Nikolay Cherkasov, Nadadur Veeraraghavan Srinath, Juergen Lang, A. O. Ibhadon, Qi Wang, V. Hessel, The Role of Heterogeneous Catalysts in the Plasma-catalytic Ammonia Synthesis, Catal. Today, 2021 362, 2-10. https://doi.org/10.1016/j.cattod.2020.06.074

Nishat Khan, Abdul Hakeem Anwer, Ameer Azam, A.O. Ibhadon, Mohammad Zain Khan, Magnesium Ferrite Spinel’s as Anode Modifier for the treatment of Congo red and Energy recovery in a Single Chambered Microbial Fuel Cell, Journal of Hazardous Materials.

Devika Vashisht, Amit Kumar, Surinder Kumar Mehta, A.O.Ibhadon, Analysis of emerging contaminants: A case study of the underground and drinking water in Chandigarh, India, Environ. Adv. 2020, 1, 100002

Shelja Sharma, A.O. Ibhadon, M. Francesconi, Surinder K, Mehta, Sasikumar Elumalai, Sushil Kansal, Ahmad Umar, Sotirios Baskoutas, Bi2WO6/C-dots/TiO2: A novel z-scheme photocatalyst for the degradation of fluoroquinolone levofloxacin from aqueous medium, Nanomater. 2020, 10,901; doi: 10.3390/nano10050910

Devika Vashisht, Shikha Sharma, Rakesh Kumar, Vaneet Saini, Vikram Saini, A.O.Ibhadon, Subash Chandra Sahoo, Shweta Sharma , S. K Mehta , Ramesh Kataria, Dehydroacetic acid Derived Schiff base as Selective and Sensitive Colorimetric Chemosensor for the Detection of Cu (II) ions in Aqueous, Microchem. Jour. 2020, 155, 104705

Shaun K. Johnston, Thomas A. Bryant, Jonathan Strong, Laura Lazzarini, A.O. Ibhadon, Maria Grazia Francesconi, Stabilization of Pd3 xIn1+x Polymorphs with Pd-like Crystal Structure and their Superior Performance as Catalysts for Semi-Hydrogenation of Alkynes, ChemCatChem 2019, 11, 1

Shelja Sharma, S. K. Mehta, A.O. Ibhadon, S. K. Kansal, Fabrication of novel Carbon Quantum Dots modified Bismuth Oxide (-Bi2O3/C-dots): Material Properties and Catalytic Applications, Jour. Colloid & Interface Sci. 2019, 533, 227–327. doi.org/10.1016/j.jcis.2018.08.056

Arun KumarRekha, S.K.Kansal, A.O.Ibhadon and S.K.Mehta, Mixed surfactant altering chain length and head group Aggregates as an effective carrier for tuberculosis drug. Chem. Phys.Lipids, 2018, 215, 11-17.

Pankaj Taneja, Shelja Sharma, Ahmad Umar, A.O.Ibhadon, Sushil Kansal, Visible-light driven photocatalytic degradation of brilliant green dye based on cobalt tungstate (CoWO4) nanoparticles, Mater. Chem. Physics, 2018, 211: 335-342. Doi: 0.1016/j.matchemphys.2018.02.041.

Shelja Sharma, Ahmad Umar, S. K. Mehta, A. O. Ibhadon and S.K.Kansal, Solar light driven photocatalytic degradation of levofloxacin using TiO2/Carbon-dots nanocomposite. New J. Chem.2018, 42, 7445-7456, doi: 10.1039/C7NJ05118B.

A.O. Ibhadon and S. Kansal, The Reduction of Alkynes over Pd-based Catalyst Materials- A Pathway to Chemical Synthesis. Jour. Chem. Eng. & Process Technol. 9, 1, 2018, doi:10.4172/2157-7048.1000376.

Pankaj Taneja, Shelja Sharma, Ahmad Umar ,Surinder Kumar Mehta, A.O. Ibhadon, Sushil Kumar Kansal, Visible-light driven photocatalytic degradation of brilliant green dye based on cobalt tungstate (CoWO4) Nanoparticles, Mater. Chem. Physics, 2018, 23, 452-487. doi.org/10.1016/j.matchemphys 2018. 02. 041.

A.O. Ibhadon, N. Chekersov, E.Rebrov (Inventors). Patent Pub. No. WO/2017/220590 (Method of Forming Patent a Coating), IPC C23C 18/12(2006.01). Dec. 2017.

A.O. Ibhadon, Rekha Bhar, Sushil Kansal, Bhawna Sachdeva, the effect of the presence of Sodium bis-(2-ethylhexyl) sulfosuccinate on the interactions between Sodium dodecyl s ulphate and Protein Papain, Jour. Molecular Liquids, 2017, 248, 751-758. doi.org/10.1016/j.molliq.2017.10.083.

Shaun K. Johnston, Nikolay Cherkasov, Elena Pérez-Barrado; Atte Ahoc, Dmitry Y. Murzinc, Grazia Francesconi; A.O. Ibhadon, Pd3Sn nanoparticles on TiO2 and ZnO supports as catalysts for semihydrogenation: Synthesis and catalytic performance, Applied Catalysis A: General, 2017, 54, 40-45.

A.O. Ibhadon and Shaun K. Johnston Nanoparticulate Pd-Sn Compounds Supported on Metal Oxides: Synthesis, Material and Catalytic Properties, Chem. Eng. Proc. Tech., 2017, 3(3): 1044.

Aandeep Kaur, G. Gupta, A.O. Ibhadon &Sushil Kansal, A Facile synthesis of silver modified ZnO Nanoplates for efficient removal of ofloxacin drug in aqueous phase under solar irradiation, Environ. Chem. Eng. 2017. doi: 10.1016/j.jece.2017.05.032.

A.O. Ibhadon, Nanoparticulate Pd3Sn on TiO2 and ZnO Supports as Catalysts for Semi Hydrogenation: Synthesis and Catalytic Performance. Synthesis and Catalysis, 2017, 2: No. 2 .10.

Kaur, A., Kansal, S.K., A.O.Ibhadon, Photocatalytic degradation of ketorolac tromethamine using Ag-doped ZnO Microplates. Jour. Mater. Sci. 2017, 52, 5256-5267. Doi. 10.1007/s10853-017-0766-6.

A.O. Ibhadon., Shaun Johnston, the Synthesis of Fine Chemicals Using Novel Catalysis.

Synthesis and Catalysis, 2017, 2: No.1:4.

RTD Success Story –Research and Innovation: An EU-funded Project (A.O. Ibhadon) has developed nitrogen fixation and Hydrogenation processes that are faster, more efficient and less polluting than current processes. Up-scaling and adoption could give Europe a greener, more competitive chemicals sector’, Retell Publications, EU Commission Research, Nov. 2016.

Nikolay Cherkasov, Evgeny V. Rebrov and A.O. Ibhadon, Novel Method for the Catalytic Coating of Tubular Reactors. European Patent No 16 175 742.2. June 2016.

Nikolay Cherkasov, Ma ’moun Al-Rawashdeh, A. O. Ibhadon, Evgeny V. Rebrov, Scale up study of Capillary Microreactors in solvent-free semihydrogenation of 2‐methyl‐3‐butyn‐2‐ol. Catal. Today, 2016, 273, 205-212, http://dx.doi.org/doi:10.1016/j.cattod.2016.03.028.

Nikolay Cherkasov, A. O. Ibhadon and Evgeny Rebrov Solvent –free semi hydrogenation of acetylene alcohols in a capillary reactor coated with a Pd-Bi/TiO2 Catalyst. Applied Catalysis A: General: 2016, 108-115. http://dx.doi.org/doi:10.1016/j.apcatb.2016.01.019.

B.S. Patil, N. Cherkasov, J. Lang, A.O. Ibhadon, V.Hessel, Q. Wang, Low Temperature Plasma-Catalytic NOx Synthesis in a Packed DBD Reactor: Effect of Support Materials and Supported Active Metal Oxides. Applied Catalysis B: Environmental. 2016, 194, 123-133. doi: 10.1016/j.apcatb.2016.04.055

Nikolay Cherkasov, A. O. Ibhadon and Evgeny Rebrov Solvent –free semi hydrogenation of acetylene alcohols in a capillary reactor coated with a Pd-Bi/TiO2 Catalyst. Applied Catal. A: General: 2016, 108-115. http://dx.doi.org/doi:10.1016/j.apcatb.2016.01.019.

Sample conference presentations since 2016

1. Eni Oko, Alex Ibhadon, Arnold Gad-Briggs, Ioannis Giannopolous and Edward Gobina, Modelling and Simulation of an on-board ammonia to hydrogen system in long haul aviation, 32nd European Symposium on Computer Aided Proces Engineering June 12-15th , 2022, Toulouse, France

2. A.O.Ibhadon, M. Ibrahim & E.Oko, Review of Catalyst –aided solvent regeneration in post-combustion CO2 capture process, Int. Conf. on Applied Energy, Nov 29-Dec 2, 2021, Bangkok, Thailand.

3. A. O. Ibhadon CATALYSISMEET 11-13th October 2021, Valencia, Spain

4. A. O. Ibhadon, reduction of Nitroarenes using FeS2 Catalysis, GC Catalysis, Dalian, China, Aug 26-28,2021

5. A. O. Ibhadon, Energy Oceania, Global Renewable Energy Researchers Meeting, London, May 07-08, 2021

6. A. O. Ibhadon, F.Teng and E.Oko, Dimethyl Ether Photoreactors GC Catalysis, China, Aug 26-8,2021

7. A new catalytic system for the highly selective reduction of halogenated Nitrobenzenes, RSC Dalton Conference, University of Warwick, 14th -16th April 2020

8. Southouse, J.P. A. O. Ibhadon and M. G. Francesconi, A new catalytic system for the highly selective reduction of halogenated Nitrobenzenes, RSC Dalton Conference, UoW, 14th -16th April 2020

9. Southouse J, Francesconi, G and Ibhadon A.O. The selective hydrogenation of Nitroarenes to Aniline Derivatives using Low cost Catalyst materials, Int. Symposium on Intermetallic Compounds in Catalysis, (IMCAT 2019), Germany 2019

10. Shaun K. Johnston, Thomas Bryant, Elena Pérez-Barrado, Jonathan Strong, Nikolay Cherkasov A.O. Ibhadon, L. Lazzarini, Atte Aho, Dmitry Y. Murzin, M. Grazia Francesconi, Pd-based Catalysts for the Semi-Hydrogenation of 2-methyl-3-buyne- 2-ol, 18th Nodic Conference on Catalysis, 2018, Denmark.

11. Jamie Southouse and A.O. Ibhadon, the Synthesis of Active Pharmaceutical Ingredients: Hydrogenation of Chloronitrobenzene, Keel University, Mercia Group Conference, Dec 19th -21st, 2017.

12. A.O. Ibhadon, Nitrogen Fixation. Manchester Energy Conference, May 2017, Manchester, UK.

Biochemical Engineering

Environment and Sustainability

Chemical Thermodynamics

Chemical Kinetics

Artificial Photosynthesis

Solar Refinery

Recent outputs

View more outputs

Conference Proceeding

Development of dense membranes for high-density hydrogen production from ammonia catalytic decomposition (cracking) for PEM fuel cells power in Long-haul Passenger Aircraft Transportation

Shehu, H., Orakwe, I., Abunomah, O., Ogunlude, P., Ogoun, E., Ramalan, M., …Gobina, E. (2022). Development of dense membranes for high-density hydrogen production from ammonia catalytic decomposition (cracking) for PEM fuel cells power in Long-haul Passenger Aircraft Transportation. In TechConnect Briefs 2022 (134-137)

Journal Article

Enhanced Wastewater Remediation Using Mesoporous Activated Wheat Straw Biochars: A Dye Removal Perspective

Priyanka, P., Vashisht, D., Ibhadon, A. O., Mehta, S. K., & Taylor, M. J. (in press). Enhanced Wastewater Remediation Using Mesoporous Activated Wheat Straw Biochars: A Dye Removal Perspective. ACS Sustainable Resource Management, https://doi.org/10.1021/acssusresmgt.3c00109

Promoted N[triple bond]N activation by oxygen and boosted ammonia production over Bi4O5Br2

Yuan, C., Lu, Z., Jiang, W., Ibhadon, A. O., & Teng, F. (2021). Promoted N[triple bond]N activation by oxygen and boosted ammonia production over Bi4O5Br2. Molecular Catalysis, 515, Article 111913. https://doi.org/10.1016/j.mcat.2021.111913

Ultra-small FeS2nanoparticles for highly efficient chemoselective transfer hydrogenation of nitroarenes

Southouse, J. P., Lazzarini, L., Ibhadon, A. O., & Francesconi, M. G. (2021). Ultra-small FeS2nanoparticles for highly efficient chemoselective transfer hydrogenation of nitroarenes. New journal of chemistry = Nouveau journal de chimie, 45(38), 17808-17815. https://doi.org/10.1039/d1nj03297f

Biosynthesis of silver nanospheres, kinetic profiling and their application in the optical sensing of mercury and chlorite ions in aqueous solutions

Vashisht, D., Sangar, S., Kaur, M., Sharma, E., Vashisht, A., Ibhadon, A. O., …Singh, K. (2021). Biosynthesis of silver nanospheres, kinetic profiling and their application in the optical sensing of mercury and chlorite ions in aqueous solutions. Environmental Research, 197, Article 111142. https://doi.org/10.1016/j.envres.2021.111142

Research interests

Industrial decarbonization via fuel switching to ammonia and hydrogen

Catalysis and Reactor Engineering renewable energy generation

Catalytic Reactors and Advanced Materials

Plasma and Microwave activation of chemical reactions

Lead investigator

Project

Funder

Grant

Started

Status

Project

Development and analysis of a novel liquid ammonia energy storage (LNHES) technology integrated into different energy systems

Funder

Net Zero Research

Grant

£40,000.00

Started

1 September 2021

Status

Ongoing

Project

Research and Development of Thallium Nitride Nanorods (Ta3N5-NRs) for CO2 reduction Photoreactors

Funder

Royal Society

Grant

£12,000.00

Started

31 July 2021

Status

Ongoing

Project

Waste Water treatment: Approaches, Management and Capacity building

Funder

British Council

Grant

£29,100.00

Started

1 March 2019

Status

Complete

Project

Synthesis of Inorganic Sensors for application in Water Monitoring and Contaminant removal

Funder

Commonwealth Scholarship Commission in the UK

Grant

£32,651.00

Started

16 September 2019

Status

Complete

Project

Industrial Hydrogen Accelerator

Funder

BEIS Department for Business, Energy & Industrial Strategy

Grant

£89,655.00

Started

15 September 2022

Status

Complete

Project

Feasibility of ammonia-to-hydrogen network in the Humber Cluster

Funder

UKRI UK Research and Innovation

Grant

£20,148.00

Started

1 October 2023

Status

Complete

Project

Luminescent C-Dots: Fabrication, Characterization And Application As Potential Photocatalyst And Fluorescent Sensor

Funder

British Council

Grant

£7,699.00

Started

28 February 2018

Status

Complete

Postgraduate supervision

1. Non-thermal plasma catalysis for renewable energy generation

2. Green ammonia and hydrogen synthesis for fuel switching in

industrial applications

3. Synthesis of green hydrogen via microwave plasma decomposition

of biomethane

4. Novel catalytic materials for energy generation from renewable

sources

5. DFT computational catalyst selection and screening for energy

generation

6. Simulation of green hydrogen production technologies

7. Low carbon materials for energy storage

8. Novel Trickle bed reactor for CO2 capture and storage

9. Development of IoT(Internet of Things) IT Platform for Peer-Peer

energy sharing

Awards and prizes

Senior Fellow, Higher Education Academy

2017 - 2035

Senior Fellow, Higher Education Academy

Visiting Professor, Panjab University

2016 - 2035

Visiting Professor, Panjab University, Chandigarh, India

Fellow, Higher Education Academy

2015 - 2035

Fellow, Higher Education Academy

Fellow , Royal Society of Chemistry

2002 - 2035

Fellow, Royal Society of Chemistry

Chartered Chemist

2002 - 2035

Chartered Chemist

Consultancy/Industry advisory role

Advisory Board Member EPSRC Centre for Energy Systems Integration (HI-ACT) HUB, University of Newcastle

2022

Advisory Board Member HI-ACT -Center for Hydrogen Integration and Accelerated Transition

External examiner role

External Examiner, Chemistry, Loughborough University

2017 - 2020

External Examiner, Chemistry, Loughborough University

Honorary position

Visiting Professor, Shoolini University, India

2016 - 2035

Visiting Professor

Scholarship role

Visiing Professor, Shoolini University, India

2016 - 2035

Visiting Professor, Shoolini University, India

Reviewer

2013 - 2035

Reviewer for the EU, Israel, Estonia, the Netherlands, Energy and Environmental Science, UKRI, MRC , ChemCatChem, Applied Catalysis B, Applied Catalysis A and the Royal Society

Reviewer, Research UK Catalysis Hub

2010

Reviewer of Institutional Proposals in Catalysis for the UK Catalysis HUB Reviewer United Kingdom Research and Innovation- MRC, EPSRC, NERC

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